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Title: Influence of microstructure on mechanical properties in cemented tungsten carbides

Thesis/Dissertation ·
OSTI ID:5495491

A wide variety of tungsten carbide based composites was investigated to determine how microstructure affects the mechanical performance of these materials, with particular emphasis placed on fracture toughness. These ceramic-metal composites contain cobalt and/or nickel binders as the ductile metal phase. The metallic phase is highly constrained in tension by the lower thermal contraction of the carbide phase during cooling from liquid phase sintering temperatures. The carbide grains are correspondingly left in compression. A simple model is used to show how these internal residual stresses cause the fracture toughness to increase as the fracture mode of tungsten carbide grains change from intergranular to transgranular. Additionally, macroscopic residual stresses are often found in cemented carbides due to rapid binder solidification, binder migration, and mechanical treatment (grinding, erosion and impact) of the surface after sintering or hot isostatic pressing. Experimental results show that macroscopic compressive stresses near the surface of the composite increase the apparent toughness.

Research Organization:
Utah Univ., Salt Lake City (USA)
OSTI ID:
5495491
Resource Relation:
Other Information: Thesis (Ph. D.)
Country of Publication:
United States
Language:
English