Effects of quenched impurities and relative antiferroelectric/ferroelectric phase stability on the incommensurately modulated polar structures of La-modified lead zirconate titanate
- Department of Materials Science and Engineering, and Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)
Structure{endash}property relationship studies have been performed in the La-modified lead zirconate titanate (PLZT) solution as a function of quenched La impurity content and Zr/Ti ratio. For Zr/Ti ratios of 90/10 and 85/15, an incommensurate antiferroelectric state was found to be stabilized with increasing La content. Temperature-dependent investigations demonstrated that the incommensurate structure becomes pinned into long-time metastable states, rather than transforming to a commensurate phase. Also, the modulation wavelength ({lambda}) was found to increase significantly with the decreasing Zr/Ti ratio and decreasing La content. The results of this study clearly demonstrate that the incommensurately modulated polar structures of PLZT are dependent on the relative antiferroelectric/ferroelectric phase stability, and the concentration of quenched La impurities. {copyright} {ital 1997 American Institute of Physics.}
- OSTI ID:
- 543744
- Journal Information:
- Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 16 Vol. 71; ISSN APPLAB; ISSN 0003-6951
- Country of Publication:
- United States
- Language:
- English
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