The cycling capability of lithium electrodes in aprotic media under passivation conditions
Journal Article
·
· Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:5406961
The galvanostatic method was used to study the cycling capability of lithium electrodes in 1 M LiClO/sub 4/ in propylene carbonate or gamma-butyrolactone (BL), 1 M LiCl in BL, and 1 M LiAsF/sub 6/ in a mixture of diethyl ether (90 vol. %) and tetrahydrofuran (10 vol. %). It is concluded from overvoltage-time relations that at a current density of 1 mA/cm/sup 2/ and modest amounts of charge passed through the electrode (1 C/cm/sup 2/), the anodic and cathodic processes occur via diffusion and migration of mobile lithium ions through the passivating film.
- Research Organization:
- Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow
- OSTI ID:
- 5406961
- Journal Information:
- Sov. Electrochem. (Engl. Transl.); (United States), Vol. 21:2
- Country of Publication:
- United States
- Language:
- English
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Study by electrode impedance spectroscopy of the passivating layer formed on the lithium electrode in aprotic media
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OSTI ID:5406961
Related Subjects
25 ENERGY STORAGE
ELECTRODES
MATERIALS TESTING
LITHIUM
ELECTROCHEMISTRY
METAL-NONMETAL BATTERIES
CARBONIC ACID ESTERS
DIFFUSION
ELECTRIC CURRENTS
LACTONES
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
OVERVOLTAGE
PASSIVATION
SERVICE LIFE
TETRAHYDROFURAN
ALKALI METAL COMPOUNDS
ALKALI METALS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CURRENTS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELEMENTS
ESTERS
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
LITHIUM HALIDES
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
TESTING
250903* - Energy Storage- Batteries- Materials
Components
& Auxiliaries
ELECTRODES
MATERIALS TESTING
LITHIUM
ELECTROCHEMISTRY
METAL-NONMETAL BATTERIES
CARBONIC ACID ESTERS
DIFFUSION
ELECTRIC CURRENTS
LACTONES
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
OVERVOLTAGE
PASSIVATION
SERVICE LIFE
TETRAHYDROFURAN
ALKALI METAL COMPOUNDS
ALKALI METALS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CURRENTS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELEMENTS
ESTERS
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
LITHIUM HALIDES
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
TESTING
250903* - Energy Storage- Batteries- Materials
Components
& Auxiliaries