Silylmethylations of C{sub 60} with Grignard reagents: Selective synthesis of HC{sub 60}CH{sub 2}SiMe{sub 2}Y and C{sub 60}(CH{sub 2}SiMe{sub 2}Y){sub 2} with selection of solvents
Journal Article
·
· Journal of Organic Chemistry
- Toyohashi Univ. of Technology, Aichi (Japan); and others
The search for biologically active compounds requires the further research into fullerene derivatives and their potential utility in materials science. This paper concerns the addition of Grignard reagents unexpectedly provided two types of silicon-containing fullerene derivatives. Selective preparation of these derivatives is dependent on the appropriate solvent. 2 figs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 539170
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 6 Vol. 59; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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