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Influence of selenium deficiency on rat cardiac glutathione metabolism during hydroperoxide infusion

Conference · · Fed. Proc., Fed. Am. Soc. Exp. Biol.; (United States)
OSTI ID:5382005

Selenium-deficient (O Se) rats have decreased cardiac glutathione peroxidase (GSH-Px) activity. As a result, hydroperoxides cannot be detoxified effectively. The authors examined the effect of t-butylhydroperoxide (BuOOH) infusion on cardiac glutathione (G) pools in O Se and control (C) isolated perfused hearts. Hearts from male rats were perfused with oxygenated Krebs-Henseleit buffer by the Langendorff method. After 20 min, 30 ..mu..M BuOOH was infused for 20 min. The heart was freeze-clamped and intracellular GSH, GSSG and GSH-protein mixed disulfide (PS-SG) concentrations were determined. Recoverable G from hearts perfused with buffer only was 1180 + 180 nmol/g and 1340 +/- 95 nmol/g for C and O Se, respectively. C hearts had a 65% decrease in GSH. This was accounted for by GSSG and PS-SG formation and GSSG release to the perfusate. BuOOH infusion into the O Se heart did not increase intracellular GSSG, but decreased GSH by 24%. The fall in GSH was not accounted for by PS-SG or by GSH or GSSG release to the perfusate. These results suggest that there is a mechanism other than GSH-Px by which GSH and hydroperoxides interact in the O Se heart.

Research Organization:
Univ. of Texas Health Science Center, San Antonio
OSTI ID:
5382005
Report Number(s):
CONF-8604222-
Journal Information:
Fed. Proc., Fed. Am. Soc. Exp. Biol.; (United States), Journal Name: Fed. Proc., Fed. Am. Soc. Exp. Biol.; (United States) Vol. 45:3; ISSN FEPRA
Country of Publication:
United States
Language:
English