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Inductively coupled plasma etching of III-V nitrides in CH{sub 4}/H{sub 2}/Ar and CH{sub 4}/H{sub 2}/N{sub 2} chemistries

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1837905· OSTI ID:536477
; ; ; ;  [1];  [2]; ;  [3]
  1. Univ. of Florida, Gainesville, FL (United States). Dept. of Materials Science and Engineering
  2. Sandia National Labs., Albuquerque, NM (United States)
  3. PlasmaTherm IP, St. Petersburg, FL (United States)

Inductively coupled plasma (ICP) etching of GaN, AlN, InN, InGaN, and InAlN was investigated in CH{sub 4}/H{sub 2}/Ar and Ch{sub 4}/H{sub 2}/N{sub 2} plasmas as a function of dc bias, ICP power, and pressure. The etch rates were generally quite low, as is common for III-nitrides in CH{sub 4}-based chemistries. In CH{sub 4}/H{sub 2}/Ar plasmas, the etch rates increased with increasing dc bias. At low radio frequency power (150 W), the etch rates increased with increasing ICP power, while at 350 W radio frequency power, a peak was found between 500 and 750 W ICP power. The dc bias was found to increase with increasing pressure. The etch rates in the CH{sub 4}/H{sub 2}/N{sub 2} chemistry were significantly lower, with a peak at 500 W ICP power. The etched surfaces were smooth, while selectivities of etch were {le} 6 for InN over GaN, AlN, InGaN, and InAlN under all conditions.

Research Organization:
Sandia National Laboratory
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
536477
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 8 Vol. 144; ISSN 0013-4651; ISSN JESOAN
Country of Publication:
United States
Language:
English

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