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High light-to-energy conversion efficiencies for solar cells based on nanostructured ZnO electrodes

Journal Article · · Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical
DOI:https://doi.org/10.1021/jp962918b· OSTI ID:535437

Photoelectrochemical properties of nanostructured ZnO thin film electrodes have been investigated in the UV and visible regions. For films consisting of 15 nm large undoped crystallites a maximum monochromatic current conversion efficiency of 58% was obtained in the visible using a ruthenium-based dye as a sensitizer. The overall solar energy conversion efficiency for this film was 2%. In comparison, sensitized films consisting of 150 nm large Al-doped crystallites yield a monochromatic current conversion efficiency of 31% and an overall solar energy conversion efficiency of 0.5%. The study also shows that nanostructured ZnO may give high efficiencies in the UV region, approaching unity for the Al-doped films. 20 refs., 4 figs.

OSTI ID:
535437
Journal Information:
Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical, Journal Name: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical Journal Issue: 14 Vol. 101; ISSN 1089-5647; ISSN JPCBFK
Country of Publication:
United States
Language:
English