Thermodynamics of aqueous sodium sulfate from the temperatures 273 K to 373 K and mixtures of aqueous sodium sulfate and sulfuric acid at 298. 15 K

Conference · Mon Jul 01 04:00:00 EDT 1991

OSTI ID:5321875

Hovey, J K; Pitzer, K S ^[1]; Rard, J A ^[2]

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1. Lawrence Berkeley Lab., CA (United States)
2. Lawrence Livermore National Lab., CA (United States)

New isopiestic vapor-pressure measurements on the aqueous system {l brace}(1{minus}y)H{sub 2}SO{sub 4}+yNA{sub 2}SO{sub 4}{r brace} along with earlier experimental investigations that span the range from y=0 to y=1 and infinitely dilute to supersaturated molalities have been analyzed in terms of the Pitzer ion-interaction model. Refined ion-interaction parameters for aqueous sodium sulfate valid over the temperature range 273 K to 373 K have been calculated and used for analyzing results for mixtures containing sulfuric acid and sodium sulfate at 298.15 K. Analysis of experimental results for these aqueous mixtures required explicit consideration of the dissociation reaction of bisulfate ion. Previous treatments of aqueous sulfuric acid and subsequently the bisulfate dissociation equilibrium valid in the range 273 K to 343 K were employed as a first approximation in representing the mixed solutions. Two sets of Pitzer ion-interaction parameters are presented for (sodium sulfate + sulfuric acid). The validity of the first set is limited in ionic strength and molality to saturated solutions of pure aqueous sodium sulfate (4 mol{center dot}kg{sup {minus}1}). The second set of parameters corresponds to a slightly less precise representation but is valid over the entire range of experimental results considered. Both sets of parameters provide a more complete description of pure sulfuric acid solutions because of the removal of various redundancies of ion-interaction parameters. The specific ion-interaction terms used and the overall fitting procedure are described as well as selected examples of relevant thermodynamic calculations in the mixed system Na{sub 2}SO{sub 4}-H{sub 2}SO{sub 4}-H{sub 2}O. 33 refs., 6 figs., 5 tabs.

• Research Organization: Lawrence Berkeley Lab., CA (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AC03-76SF00098
• OSTI ID: 5321875
• Report Number(s): LBL-31194; CONF-9107180--2; ON: DE92011729
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACID SULFATES
ALKALI METAL COMPOUNDS
AQUEOUS SOLUTIONS
BINARY MIXTURES
DISPERSIONS
DISSOCIATION
ENERGY
FREE ENTHALPY
HYDROGEN COMPOUNDS
INORGANIC ACIDS
MIXTURES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SODIUM COMPOUNDS
SODIUM SULFATES
SOLUTIONS
SULFATES
SULFUR COMPOUNDS
SULFURIC ACID
THERMODYNAMIC ACTIVITY
THERMODYNAMIC PROPERTIES
VAPOR PRESSURE