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U.S. Department of Energy
Office of Scientific and Technical Information

Integrated coking-gasification process with mitigation of bogging and slagging

Patent ·
OSTI ID:5290610
This patent describes improvement in a fluid coking-gasification process for converting heavy hydrocarbonaceous materials to lower boiling products. It comprises introducing a heavy hydrocarbonaceous chargestock into a coking zone comprised of a bed of fluidized solids maintained at fluid coking conditions, including a temperature from about 850{degrees} to 1200{degrees} F. and a total pressure of up to about 150 psig, to produce a vapor phase product including normally liquid hydrocarbons, and coke, the coke depositing on the fluidized solids; introducing a portion of the solids with coke deposited thereon into a heating zone comprised of a fluidized bed of solid particles and operated at a temperature greater than the coking zone; and recycling a portion of the heated solids from the heating zone to the coking zone; introducing a second portion of the heated solids from the heating zone to a gasification zone comprised of a fluidized bed of solid particles and maintained at a temperature greater than the heating zone; and reacting the second portion of heated solids in the gasification zone with steam and an oxygen-containing gas; the improvement comprises using an effective amount of calcium silicate to prevent bogging and/or slagging, wherein the calcium silicate is introduced into the process by one or more procedures selected from: mixing it with the heavy hydrocarbonaceous chargestock prior to introduction into the coking zone; adding it directly into the gasification zone; and mixing it with the portion of heated solids passing from the heating zone to the gasification zone.
Assignee:
Exxon Research and Engineering Co., Florham Park, NJ (United States)
Patent Number(s):
A; US 5094737
Application Number:
PPN: US 7-591335
OSTI ID:
5290610
Country of Publication:
United States
Language:
English