Radiolysis of trichlorobenzene. IV. Radiolysis of trichlorobenzene in organic solutions

Journal Article · Sat Oct 31 23:00:00 EST 1987 · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:5285725

Zagorets, P A; Filippov, E A; Bulgakova, G P; Dakalova, T S; Kalabukhova, E Yu

Results are given for the study of the yield of HCl in the radiolysis of trichlorobenzene (TCB) and lower chlorobenzenes, dichlorobenzene and chlorobenzene, in the presence of an organic component: octane, benzene, nitrobenzene, trioctylamine, triethylamine and decyl alcohol. In all the solutions, there was observed a sensitizing action by the organic component on the yield of HCl from TCB. The possible sensitization mechanisms are discussed. It was shown that the inhibitor should be sought from among compounds having a low affinity to electron and low ionization an electronic excitation potentials.

• OSTI ID: 5285725
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 29:2; ISSN SVRDA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ACTIVATION ENERGY
ALCOHOLS
ALKANES
AMINES
AROMATICS
BENZENE
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CHLORINATED AROMATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
DECANOLS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRON TRANSFER
ENERGY
ENERGY-LEVEL TRANSITIONS
EXCITATION
GAMMA RADIATION
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INHIBITION
INORGANIC ACIDS
IONIZATION POTENTIAL
IONIZING RADIATIONS
KINETICS
NITRO COMPOUNDS
NITROBENZENE
OCTANE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADIOLYSIS
REACTION KINETICS
SOLVENTS
YIELDS