Dialkyl (3-(1-silatranyl)propyl) phosphoramidates and their thionic and thiolic analogs

Journal Article · Mon Nov 10 04:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5277326

Voronkov, M G; Kudyakov, N M; Albanov, A I

The reactions of (3-aminopropyl)triethoxysilane with dialkyl phosphorochloridates and their thionic and thiolic analogs lead to the corresponding dialkyl (3-(triethoxysilyl)propyl)phosphoramidates and their thio analogs. Methods were developed for the synthesis of dialkyl (3-(1-silatranyl)propyl)phosphoramidates and their thionic and thiolic analogs by the transetherification of the corresponding dialkyl (3-(triethoxysilyl)propyl)phosphoramidates and their thio analogs with triethanolamine. The reactions and structures of the products are confirmed by IR and full NMR spectroscopy using hydrogen 1, phosphorus 31, carbon 13, and silicon 29 chemical shift, coupling constant, and line structure analysis.

• Research Organization: Irkut-sk Institute of Organic Chemistry (USSR)
• OSTI ID: 5277326
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:5; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AMIDES
AMINES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
COMPLEXES
COUPLING
COUPLING CONSTANTS
ENERGY LEVELS
ETHERS
EVEN-ODD NUCLEI
EXCITED STATES
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
LINE WIDTHS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
SILICON 29
SILICON COMPLEXES
SILICON ISOTOPES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
VIBRATIONAL STATES