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Comparison of the structures and elicitor activities of a synthetic and a mycelial-wall-derived hexa(. beta. -D-glucopyranosyl)-D-glucitol

Journal Article · · J. Biol. Chem.; (United States)
OSTI ID:5273051

The elicitor activity and structural characteristics of chemically synthesized hepta- and octa-..beta..-D-glucopyranosides were compared with the same properties of an elicitor-active mycelial-wall-derived hexa(..beta..-D-glucopyranosyl)-D-glucitol. The specific elicitor activities, retention times on reversed-phase liquid chromatography columns, glycosyl-linkage compositions, /sup 1/H NMR analyses, and glycosyl-sequence analyses of the synthetic and mycelial-wall-derived hexa(..beta..-D-glucopyranosyl)-D-glucitols were indistinguishable. This work provided conclusive proof that elicitor activity was associated with the structure proposed for the elicitor-active mycelial-wall-derived hexa(..beta..-D-glucopyranosyl)-D-glucitol. 14 references, 4 figures, 4 tables.

Research Organization:
Univ. of Colorado, Boulder
DOE Contract Number:
AC02-76ER01426
OSTI ID:
5273051
Journal Information:
J. Biol. Chem.; (United States), Journal Name: J. Biol. Chem.; (United States) Vol. 259:18; ISSN JBCHA
Country of Publication:
United States
Language:
English