Decomposition of CH/sub 3/TiCl/sub 3/ complexes with pyridine-based ligands
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5251433
The kinetics and mechanisms of the reactions of CH/sub 3/TiCl/sub 3/ with pyridine, ..gamma..-picoline, and 4-vinylpyridine were investigated. It was found that a homolytic break of the Ti-C bond takes place in CH/sub 3/TiCl/sub 3/ complexes with pyridine. It was established that, as a consequence of the decomposition of the Ti-C bond in CH/sub 3/TiCl/sub 3/ complexes with 4-vinylpyridine and with ..gamma..-picoline, the pyridine ring is metallized. The rate constants of this process were determined.
- Research Organization:
- Institute of Chemical Physics, Chernogolovka (USSR)
- OSTI ID:
- 5251433
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:2; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6614617
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKANES
AZINES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DECOMPOSITION
DEUTERATION
DEUTERIUM COMPOUNDS
DISSOCIATION
ENERGY
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN TRANSFER
ISOTOPE RATIO
ISOTOPIC EXCHANGE
KINETICS
METHANE
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
QUANTITY RATIO
REACTION KINETICS
SPECTRA
TITANIUM CHLORIDES
TITANIUM COMPLEXES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKANES
AZINES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DECOMPOSITION
DEUTERATION
DEUTERIUM COMPOUNDS
DISSOCIATION
ENERGY
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN TRANSFER
ISOTOPE RATIO
ISOTOPIC EXCHANGE
KINETICS
METHANE
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
QUANTITY RATIO
REACTION KINETICS
SPECTRA
TITANIUM CHLORIDES
TITANIUM COMPLEXES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS