Copper(II) chelates as catalysts in carbamic ester formation

Journal Article · Sun Aug 10 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5249155

Solozhenko, E G; Panova, G V; Potapov, V M

In the reaction of phenyl isocyanate with methanol the catalytic activity of Cu(II) chelates with enamino ketones and Schiff bases depends on the steric structure of the chelate entity and the character of the substituents in the ligands. The catalytic activities of dinuclear Cu(II) chelates are higher than the activities of allied mononuclear chelates.

• Research Organization: M. V. Lomonosov Moscow State Univ. (USSR)
• OSTI ID: 5249155
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTRA
ALCOHOLS
CARBAMIC ACID ESTERS
CARBOXYLIC ACID ESTERS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHELATES
COMPARATIVE EVALUATIONS
COMPLEXES
COPPER COMPOUNDS
ESTERS
HYDROXY COMPOUNDS
ISOCYANATES
KETONES
MATERIALS TESTING
METHANOL
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
SPECTRA
STEREOCHEMISTRY
SYNTHESIS
TESTING
TRANSITION ELEMENT COMPOUNDS