The crystalline phases present in carbon cathodes of discharged Li/SOCl/sub 2/-LiAlCl/sub 4/ cells

Journal Article · Mon May 01 04:00:00 EDT 1989 · Journal of the Electrochemical Society; (USA)

DOI:https://doi.org/10.1149/1.2096908· OSTI ID:5245158

Williams, R M; Surampudi, S; Bankston, C P ^[1]

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1. Jet Propulsion Lab., California Institute of Technology, Pasadena, CA (US)

The authors describe the x-ray diffraction patterns of 100% discharged Schawinigan black cathodes from Li/SOCl/sub 2-/LiAlCl/sub 4/ cells obtained using a high resolution Guinier camera. The previous assignments of the diffraction lines to Li/sub 2/O/sub 2/ and rhombohedral sulfur are all found to be incorrect; all sharp Bragg diffraction lines not assignable to anhydrous LiCl can be assigned to LiCl1 . H/sub 2/O.

• OSTI ID: 5245158
• Journal Information: Journal of the Electrochemical Society; (USA), Journal Name: Journal of the Electrochemical Society; (USA) Vol. 136:5; ISSN JESOA; ISSN 0013-4651
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250902 -- Energy Storage-- Batteries-- Performance & Testing
36 MATERIALS SCIENCE
360602* -- Other Materials-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
CARBON
CATHODES
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTALS
DIFFRACTION
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM OXIDES
LITHIUM-CHLORINE BATTERIES
LITHIUM-SULFUR BATTERIES
METAL-GAS BATTERIES
METAL-NONMETAL BATTERIES
NONMETALS
OXIDES
OXYGEN COMPOUNDS
PERFORMANCE
PHASE STUDIES
SCATTERING
X-RAY DIFFRACTION