Cathodic passivation of Mo in 1. 5 M LiAlCl/sub 4//SOCl/sub 2/
Conference
·
OSTI ID:5149550
Cathodic passivation of Mo in 1.5 M LiAlCl/sub 4//SOCl/sub 2/ is initially limited by Fowler-Nordheim tunnel emission of electrons from the metal to localized states in the LiCl film. After the establishment of a space-charge layer at the Mo/LiCl interface, film growth becomes kinetically limited by impurity (hopping) conduction of electrons through the localized states. A simplified electronic structure of the Mo/LiCl/SOCl/sub 2/ half-cell is presented.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (USA)
- DOE Contract Number:
- AC04-76DP00789
- OSTI ID:
- 5149550
- Report Number(s):
- SAND-86-1097C; CONF-861068-10; ON: DE87000976
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRONIC STRUCTURE
ELEMENTS
FILMS
HALIDES
HALOGEN COMPOUNDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM-SULFUR BATTERIES
METAL-NONMETAL BATTERIES
METALS
MOLYBDENUM
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PASSIVATION
THIONYL CHLORIDES
TRANSITION ELEMENTS
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRONIC STRUCTURE
ELEMENTS
FILMS
HALIDES
HALOGEN COMPOUNDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM-SULFUR BATTERIES
METAL-NONMETAL BATTERIES
METALS
MOLYBDENUM
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PASSIVATION
THIONYL CHLORIDES
TRANSITION ELEMENTS