Photoelectron angular distributions from the subshells of high-Z elements
Numerical predictions are obtained, within a relativistic multipole central-field approximation calculation, for the radial matrix elements and resulting angular distributions of photoelectrons ejected from inner through outer subshells of uranium and for photoelectron energies from near threshold (1 eV) to 100 keV. Some data are also presented for outer subshells of mercury. We confirm that for inner shells higher-multipole effects persist to low energies, while we find that for outer shells such effects become small. For uranium inner ns subshells the asymmetry parameter ..beta../sub n/s differs from its nonrelativistic value 2, but not more than 30% (for n<4), until the energy becomes quite high (the radial matrix elements for ns ..-->.. epsilonp/sub 1/2/ and ns ..-->.. epsilonp/sub 3/2/ transitions for these inner shells are similar). For outer s subshells relativistic spin-orbit splittings cause large deviations from the nonrelativistic predictions which can be understood from the magnitudes, zeros, and splittings of the two radial matrix elements. For U 6p/sub 1/2/ and 6p/sub 3/2/, ..beta../sub 6p/ has the same qualitative features found in nonrelativistic calculations for outer p shells of other high-Z elements, but the angular distributions from the two states do differ in detail. Such differences in angular distributions of the photoelectrons from the two j substates of given l become smaller for inner p shells. For outer d and f subshells the asymmetry parameter oscillates with photoelectron energy in a manner similar to that found by Manson in nonrelativistic dipole d-subshell calculations, and no qualitatively important relativistic effects have been identified; this is due to the decrease of the fine-structure-splitting interval with increasing angular momentum.
- Research Organization:
- Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, Pennsylvania 15260
- OSTI ID:
- 5239755
- Journal Information:
- Phys. Rev., A; (United States), Journal Name: Phys. Rev., A; (United States) Vol. 22:2; ISSN PLRAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTINIDES
ANGULAR DISTRIBUTION
ASYMMETRY COEFFICIENTS
COUPLING
DISTRIBUTION
ELECTRON EMISSION
ELEMENTS
EMISSION
ENERGY RANGE
ENERGY-LEVEL TRANSITIONS
EV RANGE
INTERMEDIATE COUPLING
KEV RANGE
L-S COUPLING
MERCURY
METALS
MULTIPOLE TRANSITIONS
PHOTOELECTRIC EMISSION
RELATIVISTIC RANGE
URANIUM