Transport properties of the oxides Y/sub 1/. sqrt. /sub x/Pr/sub x/Ba/sub 2/Cu/sub 3/O/sub 7/. sqrt. /sub delta/ (0less than or equal toxless than or equal to1): Effects of band filling and lattice distortion on superconductivity
The oxides with composition Y/sub 1/..sqrt../sub x/Pr/sub x/Ba/sub 2/(Cu/sub 3/O/sub 7/..sqrt../sub delta/)(0less than or equal toxless than or equal to1) 7-delta (0less than or equal toxless than or equal to1) are characterized by x-ray diffraction, resistivity (rho) and thermoelectric power (S) measurements. X-ray diffraction shows an orthorhombically distorted perovskite structure for all compositions, the pseudotetragonality increasing with x. The substitution of the tetravalent Pr for the trivalent Y atom increases the band filling in these materials. As a consequence, the superconducting transition temperature is progressively decreased with increasing x, and S significantly increases. Thermopower and resistivity measurements indicate that these oxides have relatively narrow bands and that the electronic correlations dominate their properties
- Research Organization:
- Departamento de Quimica, Instituto de Ciencias e Engenharia Nuclear(enLaboratorio Nacional de Engenharia e Technolgia Industrial P-2686 Sacavem Codex, Portugal
- OSTI ID:
- 5220997
- Journal Information:
- Phys. Rev. B: Condens. Matter; (United States), Journal Name: Phys. Rev. B: Condens. Matter; (United States) Vol. 37:13; ISSN PRBMD
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
360204* -- Ceramics
Cermets
& Refractories-- Physical Properties
656100 -- Condensed Matter Physics-- Superconductivity
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ALKALINE EARTH METAL COMPOUNDS
BARIUM COMPOUNDS
BARIUM OXIDES
CHALCOGENIDES
COHERENT SCATTERING
COPPER COMPOUNDS
COPPER OXIDES
CRYSTAL STRUCTURE
DIFFRACTION
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
OXIDES
OXYGEN COMPOUNDS
PARAMETRIC ANALYSIS
PEROVSKITES
PHYSICAL PROPERTIES
PRASEODYMIUM COMPOUNDS
PRASEODYMIUM OXIDES
RARE EARTH COMPOUNDS
SCATTERING
SUPERCONDUCTIVITY
THERMODYNAMIC PROPERTIES
THERMOELECTRIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TRANSITION TEMPERATURE
X-RAY DIFFRACTION
YTTRIUM COMPOUNDS
YTTRIUM OXIDES