Investigation of the possibility of intermediate formation of allyl alcohol in the process of oxidative acetoxylation of propylene on a palladium-copper zeolite catalyst
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
The formation of allyl acetate in reactions of oxidative acetoxylation of propylene by labeled acetic acid and esterification of labeled acetic acid by allyl alcohol on a Pd, Cu-zeolite catalyst occur with complete conservation of the labeled oxygen of the original labeled acetic acid in the reaction product. The authors propose a reaction scheme for the oxidative acetoxylation of propylene, providing for the formation of allyl alcohol as an intermediate compound, present in a chemisorbed state in the form of a complex with a Pd atom. The gas-phase oxidative acetoxylation of propylene is an industrial method of producing allyl acetate.
- Research Organization:
- N.D. Zelinskii Institute of Organic Chemistry
- OSTI ID:
- 5163812
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:6; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetics and mechanism of the oxidation of propylene to allyl acetate in solutions of palladium clusters
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Journal Article
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Sun May 01 00:00:00 EDT 1988
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OSTI ID:5922960
Study of the kinetics and mechanism of oxidative acetoxylation of propylene catalyzed by Pd(III)
Journal Article
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Fri Jul 01 00:00:00 EDT 1988
· Kinet. Catal. (Engl. Transl.); (United States)
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Aspects of selective oxidation and ammoxidation mechanisms over bismuth molybdate catalysts--2. Allyl alcohol as a probe for the allylic intermediate
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Thu May 01 00:00:00 EDT 1980
· J. Catal.; (United States)
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OSTI ID:6319918
Related Subjects
02 PETROLEUM
020400* -- Petroleum-- Processing
ACETATES
ACETIC ACID
ACETYLATION
ACYLATION
ALCOHOLS
ALKENES
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COPPER COMPOUNDS
ESTERIFICATION
EVEN-EVEN NUCLEI
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
ISOTOPES
KINETICS
LABELLING
LIGHT NUCLEI
MATERIALS
MINERALS
MONOCARBOXYLIC ACIDS
NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN 18
OXYGEN ISOTOPES
PALLADIUM COMPOUNDS
PROPYLENE
REACTION INTERMEDIATES
REACTION KINETICS
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
ZEOLITES
020400* -- Petroleum-- Processing
ACETATES
ACETIC ACID
ACETYLATION
ACYLATION
ALCOHOLS
ALKENES
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COPPER COMPOUNDS
ESTERIFICATION
EVEN-EVEN NUCLEI
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
ISOTOPES
KINETICS
LABELLING
LIGHT NUCLEI
MATERIALS
MINERALS
MONOCARBOXYLIC ACIDS
NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN 18
OXYGEN ISOTOPES
PALLADIUM COMPOUNDS
PROPYLENE
REACTION INTERMEDIATES
REACTION KINETICS
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
ZEOLITES