Formation, structure, and material properties from the reaction product of M(OCHMe{sub 2}){sub 4} (M = Ti, Zr) and HOAc
Book
·
OSTI ID:51541
- Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry
- Sandia National Labs., Albuquerque, NM (United States). Advanced Materials Lab.
- Univ. of California, Irvine, CA (United States). Dept. of Chemistry
In an attempt to ultimately control the characteristics of the PZT films, the authors have decided to investigate some of the basic chemistry associated with these solutions. Frequently, these solutions have been generated from Group 4 metal alkoxides in acetic acid (HOAc). Therefore, studies of the simple reactivity between M(OCHMe{sub 2}){sub 4} (M = Ti, Zr) and HOAC have been undertaken. These reactions were monitored by {sup 1}H, {sup 13}C, {sup 17}O NMR, FT-IR, TGA/DTA, and single crystal X-ray, studies. Films were produced from spin-coat deposition of crystalline material (from the titanium reaction) in toluene and aged solutions as well.
- OSTI ID:
- 51541
- Report Number(s):
- CONF-940411--; ISBN 1-55899-246-4
- Country of Publication:
- United States
- Language:
- English
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