Formation, structure, and material properties from the reaction product of M(OCHMe{sub 2}){sub 4} (M=Ti, Zr) and HOAc
Conference
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OSTI ID:10160248
- New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemistry
- Sandia National Labs., Albuquerque, NM (United States)
- California Univ., Irvine, CA (United States). Dept. of Chemistry
In an attempt to ultimately control the characteristics of the solutions used for PZT films, we have decided to investigate some of the basic chemistry associated with these mixtures. Frequently these solutions have been generated from Group IV metal alkoxides in acetic acid (HOAc). Therefore, studies of the simple reactivity between M(OCHMe{sub 2}){sub 4}(M = Ti, Zr) and HOAc have been undertaken. These reactions were monitored by {sup 1}H, {sup 13}C, {sup 17}O NMR, FT-IR, TGA/DTA, and single crystal X-ray studies. Films were produced by spin-coat deposition of crystalline material (from the titanium reaction) dissolved in toluene and from aged solutions as well.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 10160248
- Report Number(s):
- SAND--94-0988C; CONF-940411--33; ON: DE94013774; BR: GB0103012
- Country of Publication:
- United States
- Language:
- English
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