3-quantum transition probabilities in the. nu. /sub 3/ manifold of UF/sub 6/ and the assignment of 3. nu. /sub 3/ in the observed infrared spectrum
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:5121275
Although there are two F/sub 1u/ components in 3..nu../sub 3/ of UF/sub 6/ and transitions are allowed from the vibrational ground state to both, only a single band has been observed in the ir spectrum. These two states may be identified in a Cartesian representation of the normal coordinates as 3..nu../sub 3x/ and 2..nu../sub 3x/+..nu../sub 3y/; on the basis of calculated intensities, the observed transition has been assigned to 3..nu../sub 3x/. The calculation of the dipole strengths required us to derive the octahedral splitting parameters G/sub 33/ and T/sub 33/ and these have been used to calculate the anharmonic splittings in the ..nu../sub 3/ vibrational manifolds of /sup 238/UF/sub 6/ and /sup 235/UF/sub 6/.
- Research Organization:
- Molecular Spectroscopy Laboratory, Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455
- OSTI ID:
- 5121275
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 68:6; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Interacting band analysis of the high-resolution spectrum of the 3nu/sub 3/ manifold of SF/sub 6/
Measurement and analysis of the infrared-active stretching fundamental (. nu. /sub 3/) of UF/sub 6/
nu. /sub 3/ vibrational ladder of SF/sub 6/
Journal Article
·
Wed Dec 31 23:00:00 EST 1980
· J. Mol. Spectrosc.; (United States)
·
OSTI ID:6312641
Measurement and analysis of the infrared-active stretching fundamental (. nu. /sub 3/) of UF/sub 6/
Journal Article
·
Mon Jul 01 00:00:00 EDT 1985
· J. Chem. Phys.; (United States)
·
OSTI ID:5548381
nu. /sub 3/ vibrational ladder of SF/sub 6/
Journal Article
·
Wed Dec 31 23:00:00 EST 1980
· Opt. Lett.; (United States)
·
OSTI ID:6876717
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
ACTINIDE COMPOUNDS
ACTINIDE ISOTOPES
ACTINIDE NUCLEI
ALPHA DECAY RADIOISOTOPES
ENERGY LEVELS
EVEN-EVEN NUCLEI
EVEN-ODD NUCLEI
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HEAVY NUCLEI
INFRARED SPECTRA
ISOMERIC TRANSITION ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
MINUTES LIVING RADIOISOTOPES
NUCLEI
RADIOISOTOPES
SPECTRA
URANIUM 235
URANIUM 238
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM HEXAFLUORIDE
URANIUM ISOTOPES
VIBRATIONAL STATES
YEARS LIVING RADIOISOTOPES
400102* -- Chemical & Spectral Procedures
ACTINIDE COMPOUNDS
ACTINIDE ISOTOPES
ACTINIDE NUCLEI
ALPHA DECAY RADIOISOTOPES
ENERGY LEVELS
EVEN-EVEN NUCLEI
EVEN-ODD NUCLEI
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HEAVY NUCLEI
INFRARED SPECTRA
ISOMERIC TRANSITION ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
MINUTES LIVING RADIOISOTOPES
NUCLEI
RADIOISOTOPES
SPECTRA
URANIUM 235
URANIUM 238
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM HEXAFLUORIDE
URANIUM ISOTOPES
VIBRATIONAL STATES
YEARS LIVING RADIOISOTOPES