nu. /sub 3/ vibrational ladder of SF/sub 6/

Journal Article · Wed Dec 31 23:00:00 EST 1980 · Opt. Lett.; (United States)

DOI:https://doi.org/10.1364/OL.6.000039· OSTI ID:6876717

Patterson, C W; Krohn, B J; Pine, A S

From an analysis of the high-resolution spectrum of the 3..nu../sub 3/ manifold of SF/sub 6/, we have determined the anharmonicity constants to be (in reciprocal centimeters) X/sub 33/=-1.7426, G/sub 33/=0.9188, and T/sub 33/=-0.24635. By using these constants, one can for the first time to our knowledge accurately predict the energies of the lower-vibrational sublevels of the ..nu../sub 3/ ladder and determine the pathways for multiple-photon absorption.

• Research Organization: Theoretical Division, Los Alamos Scientific Laboratory, University of California, Los Alamos, New Mexico 87545
• OSTI ID: 6876717
• Journal Information: Opt. Lett.; (United States), Journal Name: Opt. Lett.; (United States) Vol. 6:1; ISSN OPLED
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360603* -- Materials-- Properties
ANHARMONIC CRYSTALS
CRYSTALS
DATA
ENERGY LEVELS
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
LASER SPECTROSCOPY
LATTICE VIBRATIONS
NUMERICAL DATA
RESONANCE
SPECTROSCOPY
SULFUR COMPOUNDS
SULFUR FLUORIDES
THEORETICAL DATA
VIBRATIONAL STATES