N-phosphorylated ketene S,N-acetals

Journal Article · Sun Sep 20 04:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5099546

Kozlov, V A; Dol'nikova, T Yu; Grapov, A F; Mel'nikov, N N

The authors investigate the reactions of phosphorisocyanitidic and phosphorisocyanatidothioc esters with organic CH acids and determine that the products, depending on the substituent on the beta-carbon atom, are either ketene S,N-acetals or equilibrium mixtures of these and phosphorylated imino thioesters. IR spectra were determined in chloroform. H 1 and P 31 NMR spectra were determined in deuterated acetone. An analysis of the spectra, including the determination of spin-spin coupling constants, is conducted.

• Research Organization: All-Union Research Institute of Chemical Means for the Protection of Plants, Moscow (USSR)
• OSTI ID: 5099546
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:4; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETALS
ACETONE
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
ESTERS
ETHERS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOTOPES
J-J COUPLING
KETONES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
SOLVENTS
SPECTRA
STABLE ISOTOPES
SYNTHESIS