Determination of chlorinated pesticides in urine by molecular neutron activation analysis

Journal Article · Fri Apr 01 04:00:00 EST 1983 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00255a022· OSTI ID:5055372

Opelanio, L R; Rack, E P; Blotcky, A J; Crow, F W

A molecular neutron activation analysis (MoNAA) procedure employing solvent extraction and high-performance liquid chromatography separation techniques with subsequent irradiation of the eluted fractions and radioassay for /sup 38/Cl activity is applied to the determination of trace quantities of DDT and its metabolites DDA (bis(p-chlorophenyl)acetic acid), DDD (1,1-dichloro-2,2-bis(p-chlorophenyl)ethane), and DDE(1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene) in urine. Data and confirmation analyses using mass spectrometry are presented.

• Research Organization: Univ. of Nebraska, Lincoln
• DOE Contract Number: AC02-76ER01617
• OSTI ID: 5055372
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 55:4; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400101* -- Activation
Nuclear Reaction
Radiometric & Radiochemical Procedures
560300 -- Chemicals Metabolism & Toxicology
63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT.
ACTIVATION ANALYSIS
AROMATICS
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BIOLOGICAL MATERIALS
BIOLOGICAL WASTES
BODY FLUIDS
CHEMICAL ANALYSIS
CHLORINE 38
CHLORINE ISOTOPES
CHROMATOGRAPHY
DATA
DDT
EXPERIMENTAL DATA
EXTRACTION
INFORMATION
INSECTICIDES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
LIQUID COLUMN CHROMATOGRAPHY
MATERIALS
MINUTES LIVING RADIOISOTOPES
MOLECULES
NUCLEAR REACTIONS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PESTICIDES
RADIOASSAY
RADIOISOTOPES
SECONDS LIVING RADIOISOTOPES
SEPARATION PROCESSES
SOLVENT EXTRACTION
URINE
WASTES