Kinetics and mechanism of the bis(cyclopentadienyl)vanadium chloride-catalyzed amalgam reduction of carbon monoxide to methane
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5053424
A study has been made of the kinetics of the Cp/sub 2/VCl/sub 2/-catalyzed amalgam reduction of carbon monoxide to methane in dimethylformamide containing phenol as the proton donor. It is shown that reaction occurs in a thin surface layer of the amalgam, and may therefore be regarded as a typical electrochemical reaction. A kinetic scheme for the catalyzed reaction is presented.
- Research Organization:
- Academy of Sciences of the USSR, Chernogolovka
- OSTI ID:
- 5053424
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 24:1; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALLOYS
AROMATICS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
ELECTROCHEMISTRY
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
MERCURY ALLOYS
METHANE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHENOLS
PRODUCTION
REDUCTION
TRANSITION ELEMENT COMPOUNDS
VANADIUM CHLORIDES
VANADIUM COMPOUNDS
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALLOYS
AROMATICS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
ELECTROCHEMISTRY
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
MERCURY ALLOYS
METHANE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHENOLS
PRODUCTION
REDUCTION
TRANSITION ELEMENT COMPOUNDS
VANADIUM CHLORIDES
VANADIUM COMPOUNDS