Nickel-cobalt-iron-copper sulfides and arsenides in solution-collapse breccia pipes, northwestern Arizona
- Geological Survey, Denver, CO (United States)
- Sandia National Labs., Albuquerque, NM (United States)
An extensive suite of Ni-Co-Fe-Cu sulfides and arsenides lies within the matrix of solution-collapse breccias buried deep within the plateaus of the Grand Canyon region. Ceilings over large caverns in the Redwall collapsed, brecciating the overlying sandstone and forming cylindrical breccia pipes up to 300 ft in diameter that extend vertically as much as 3,000 ft. These highly permeable breccias served as a host for the precipitation of a suite of over 100 minerals, including uraninite, sphalerite, galena and various copper phases, in addition to the Ni-Co-bearing-phase discussed here. Intricately zoned crystals of small (<1 mm), euhedral Ni-Co-Fe-As-S minerals were the first to form during the second major episode of mineralization in these pipes. Several of these phases replace minerals, such as barite and anhydrite, from the first episode. Extensive microprobe work has been done on samples from two breccia pipe mines, the Hack 2 and Orphan, which are about 50 miles apart. Mineral compositions are similar except that no copper is found in the Ni-Co-Fe phases from the Hack 2 mine, while pyrites containing 1 wt % Cu are common from the Orphan, which was mined for copper. In some of these pyrites', Cu is dominant and the mineral is actually villamaninite. Pyrites from both mines characteristically contain 0.5 to 3 wt % As. Metal contents in zones pyrite-bravoite-vaesite (M[sub 1]S[sub 2]) crystals at the Hack 2 mine range from Fe[sub 1] to Fe[sub .12], Ni[sub 0] to Ni[sub .86], and Co[sub 0] to Co[sub .10]. The metal content for polydymite-siegenite-violarite averages about (Ni[sub 2.33]Co[sub .39]Fe[sub .23])(S[sub 3.9]As[sub .1]). Orphan mine pyrite-bravoite-vaesite-villamaninite ranges in composition from pure FeS[sub 2] to (Ni[sub .6]Fe[sub .21]Co[sub .17])S[sub 2], and (Cu[sub .46]Ni[sub .27]Fe[sub .21]Co[sub .13])S[sub 2]. Of all the sulfides or arsenides found in these breccia pipes, only nickeline consistently occurs as the pure end member.
- DOE Contract Number:
- AC04-76DP00789
- OSTI ID:
- 5023999
- Report Number(s):
- CONF-9305259-; CODEN: GAAPBC
- Journal Information:
- Geological Society of America, Abstracts with Programs; (United States), Vol. 25:5; Conference: 89. annual meeting of the Cordilleran Section and the 46th annual meeting of the Rocky Mountain Section of the Geological Society of America (GSA), Reno, NV (United States), 19-21 May 1993; ISSN 0016-7592
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ARIZONA
GEOLOGIC DEPOSITS
GEOCHEMISTRY
GEOLOGY
ORIGIN
ORES
ARSENIDES
BARITE
COBALT SULFIDES
COPPER SULFIDES
CRYSTALLIZATION
CRYSTALLOGRAPHY
GALENA
IRON
MINERALOGY
NICKEL SULFIDES
PYRITE
SPHALERITE
URANINITES
ARSENIC COMPOUNDS
CHALCOGENIDES
CHEMISTRY
COBALT COMPOUNDS
COPPER COMPOUNDS
DEVELOPED COUNTRIES
ELEMENTS
MATERIALS
METALS
MINERALS
NICKEL COMPOUNDS
NORTH AMERICA
OXIDE MINERALS
PHASE TRANSFORMATIONS
PNICTIDES
RADIOACTIVE MATERIALS
RADIOACTIVE MINERALS
SULFATE MINERALS
SULFIDE MINERALS
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
URANIUM MINERALS
USA
580000* - Geosciences