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Separation of boron isotopes. VI. Ethyl ether, ethyl sulfide, and triethylamine--BF/sub 3/ systems

Journal Article · · J. Phys. Chem.; (United States)
OSTI ID:5018340

The BF/sub 3/ complexes of ethyl ether, ethyl sulfide, and triethylamine were studied. Isotopic equilibrium constants for the reactions /sup 10/BF/sub 3/(g) + /sup 11/BF/sub 3/ . donor(l) reversible /sup 10/BF/sub 3/(g) + /sup 10/BF/sub 3/ . donor were measured at several temperatures for each of the three systems. Vapor pressures of the ethyl sulfide complex, and rates of exchange of boron between BF/sub 3/ and BF/sub 3/ . ET/sub 3/N were also determined.

Research Organization:
Oak Ridge National Lab., TN
OSTI ID:
5018340
Journal Information:
J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 40; ISSN JPCHA
Country of Publication:
United States
Language:
English