SEPARATION OF BORON ISOTOPES. III. THE n-BUTYL SULFIDE-BF$sub 3$ SYSTEM
Journal Article
·
· Journal of Chemical Physics (U.S.)
The gas-liquid isotopic exchange between BFsub 3/ and the n-butyl sulfide-BF/sub 3/ complex was studied as a possible system for enriching boron isotopes The single stage separation factor varied from 1.054 at -20 C to 1.033 at 26 C. B/sup 10/ concentrated in the liquid phase. The heat of association of the n-butyl sulfideboron trifluoride complex was determined to be - 12.76 sintering time 0.06 kcal/mole from a series of vapor pressure measurements of the complex made at several mole ratios of BF/sub 3/ to sulfide. (auth)
- Research Organization:
- Oak Ridge National Lab., Oak Ridge, Tenn.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-13-014937
- OSTI ID:
- 4249144
- Journal Information:
- Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 30; ISSN JCPSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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