Potentiometric studies of radiation-stimulated oxidation of sulfur dioxide by molecular oxygen

Journal Article · Tue Jul 01 00:00:00 EDT 1986 · High Energy Chem. (Engl. Transl.); (United States)

OSTI ID:5018115

Muratbekov, M B; Danilenko, A V

An application of a glass redox electrode EO-01 for potentiometric studies of the kinetics of radiation-stimulated oxidation of sulfur dioxide by molecular oxygen is investigated. Some properties of the glass electrode placed into the radiation zone are described. The kinetics of radiation-stimulated oxidation of sulfur dioxide by molecular oxygen is studied in perchloric acid. A method of calculating the radiation chemical yield of oxygen consumption is proposed and the ratios of the rate constants of intermediate reactions are calculated.

• Research Organization: Kirov Kazakh Univ.
• OSTI ID: 5018115
• Journal Information: High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 20:1; ISSN HIECA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600 -- Radiation Chemistry
500200* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION ABATEMENT
CHALCOGENIDES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ELECTRODES
ELEMENTS
EXHAUST GASES
FLUIDS
GASEOUS WASTES
GASES
GLASS
KINETICS
MATHEMATICAL MODELS
NONMETALS
OXIDATION
OXIDES
OXYGEN
OXYGEN COMPOUNDS
POLLUTION ABATEMENT
POTENTIOMETRY
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
REACTION KINETICS
REDOX POTENTIAL
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
TITRATION
WASTES
YIELDS