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Nanowear/nanomechanical testing and the role of stress in sputtered CN{sub x} overcoats

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.365562· OSTI ID:496588
; ;  [1]
  1. Department of Metallurgical and Materials Engineering and The Center for Materials for Information Technology, The University of Alabama, Tuscaloosa, Alabama 35487-0202 (United States)

a:C{endash}N{sub x} films were deposited on Si(111) wafers at ambient temperatures by reactive magnetron sputtering of C in a mixed Ar/N{sub 2} discharge. The hardness (H) and elastic modulus (E) were assessed via nanoindentation using a Berkovich diamond indenter. The nitrogenated films exhibited increased hardness and elastic moduli values compared to the amorphous carbonated films, i.e., 25 and 240 GPa to 16 and 160 GPa, respectively. A sphere-on-flat (magnetic tape) wear tester was used to assess wear scar volume losses as a function of wear time. All films were in a state of compression (intrinsic and thermal stress). The bonding, composition, and structure of the films for all the deposition conditions were assessed by micro-Raman spectroscopy, energy dispersive x-ray spectroscopy (EDX), and x-ray diffraction (XRD), respectively, and subsequently correlated to overall film properties.{copyright} {ital 1997 American Institute of Physics.}

OSTI ID:
496588
Report Number(s):
CONF-961141--
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 8 Vol. 81; ISSN JAPIAU; ISSN 0021-8979
Country of Publication:
United States
Language:
English