ESR detection of the regioisomers due to addition of methoxy and methylthio radicals to fullerene C{sub 70}
Journal Article
·
· Journal of Organic Chemistry
- Univ. of Bologna (Italy)
The authors report ESR studies of three regioisomers of the MeS-C{sub 70}{center_dot} adduct formed by photolysis. A 1:3:3:1 splitting pattern was observed for each regioisomer. A methoxy adduct of C{sub 70} was formed by photolysis of di-tert butyl peroxide in the presence of C{sub 70}, but the ESR spectra were too complicated for interpretation. Photolysis of MeOSSOMe generates an MeO{center_dot} radical which adds to C{sub 60} forming MeO-C{sub 60}{center_dot} which was studied by ESR spectrometry. 11 refs., 3 figs., 1 tab.
- OSTI ID:
- 494165
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 16 Vol. 61; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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