ESR study of spin-adducts of boron-centered carboranyl radicals with fullerene-60 and fullerene-70
Journal Article
·
· Russian Chemical Bulletin
- A.N. Nesmeyanov Institute of Organoelement Compounds, Moscow (Russian Federation); and others
Spin-adducts of boron-centered radicals, derivatives of m-carboran-12, with fullerenes C{sub 60} and C{sub 70} have been studied by ESR spectroscopy. Constants of hyperfine splitting (HFS) of an unpaired electron with {sup 10}B and {sup 11}B nuclei have been determined from the ESR spectra of C{sub 60}-B{sub 10}H{sub 9}C{sub 2}H{sub 2} radicals. Three isomeric spin-adducts were detected with different HFS constants with {sup 11}B, and g-factors were detected in the reaction of {sup {center_dot}}B{sub 10}H{sub 9}C{sub 2}H{sub 2} with C{sub 70}.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 160293
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 9 Vol. 44; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
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