Secondary Isotope Effect in the Addition of Hydrogen Atoms to Propylene- d 6
Journal Article
·
· Canadian Journal of Chemistry
Reactions of H atoms produced by mercury-photosensitized decomposition of butane and C3H6 or C3D6 were carried out at 25 deg C in mixtures of 450 mm butane and varying small amounts of olefin. The secondary isotope effect in the addition of H atoms to C3D6 and C3H6 was found to be k(D)/k(H) = 1.078 plus or minus 0.037. (D.L.C.)
- Research Organization:
- National Research Council, Ottawa
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-16-017585
- OSTI ID:
- 4834734
- Report Number(s):
- NRC-6746; 0008-4042
- Journal Information:
- Canadian Journal of Chemistry, Journal Name: Canadian Journal of Chemistry Journal Issue: 5 Vol. 40; ISSN 0008-4042
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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ISOTOPIC AND HOT RADICAL EFFECTS IN THE REACTION OF HYDROGEN ATOMS WITH ETHYLENE
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·
OSTI ID:4253290
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Journal Article
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Wed Apr 07 23:00:00 EST 1976
· J. Phys. Chem.; (United States)
·
OSTI ID:7190874