POLAROGRAPHIC BEHAVIOUR OF INDIUM IN THE PRESENCE OF TRIHYDROXYGLUTARIC ACID

Journal Article · Fri Sep 01 00:00:00 EDT 1961 · Zhur. Anal. Khim.

OSTI ID:4830385

Vinogradova, E N; An, C

The polarographic behavtor ot indium in the presence of trihydroxyglutaric acid in acid, nautral, and alkalino media was studied. The vaIue of the half-wave potental of a simple indium ion was determined in HClO/sub 4/ by the half-peak: potential during the anodic dissolutaon of and indium from an amalgam. The half-wave potential is eqia; tp 0.488 v. The effect of the concentration of trihydroxyglutaric acido on the E/sub 1/2/ of indium was studied. It was found that the regular shift of E/sub 1/2/ on changing the concentration of trihydroxyglutaric acid is observed only at pH 4 and pH ll. The coordination number p = 2 and the unstability constant for the indium-trihydroxyglutaric aeid eonnplex at pH 4 were found. K (mean) is (9.73 plus or minus 0.82) x 10/sup - 11/. It was established that the process of indium reduction at pH 11 is irreversible. A method was suggested for the polarographic determination of indium and cadmium, when present together, in trihydroxyglutaric acid at pH 3 and pH 9. (auth)

• Research Organization: Moscow State Univ.
• NSA Number: NSA-16-001715
• OSTI ID: 4830385
• Journal Information: Zhur. Anal. Khim., Vol. Vol: 16; Other Information: Orig. Receipt Date: 31-DEC-62
• Country of Publication: Country unknown/Code not available
• Language: Russian

Related Subjects

CHEMISTRY
ACIDITY
ALLOYS
ANODES
BEHAVIOR
CADMIUM
COMPLEXES
CONVECTION
ELECTRIC POTENTIAL
ELECTRONS
ENRICHMENT
EQUATIONS
FLUID FLOW
HYDROXIDES
INDIUM
MAGNETIC FIELDS
MAGNETOHYDRODYNAMICS
MATHEMATICS
NUMERICALS
ORGANIC ACIDS
PERCHLORIC ACID
POLAROGRAPHY
QUANTITATIVE ANALYSIS
QUANTITY RATIO
REDUCTION
SOLUBILITY
STABILITY
TEMPERATURE
THERMAL CONDUCTIVITY
VISCOSITY