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Titration of Uranium with Potassium Dichromate. Determination of Disproportionality Effects

Journal Article · · Analytical Chemistry
DOI:https://doi.org/10.1021/ac60181a029· OSTI ID:4814445

The indicator, diphenylaminesulfonic acid, is shown to be responsible for the disproportionality observed between milligrams of uranium titrated and milliliters of potassium dichromate used, when the titration end point is determined visually. Determining the end point potentiometrically, the discrepancy was eliminated within certain limits. and optimum conditions were found for the potentiometric titration of as little as 10 mg of uranium.

Research Organization:
Atomic Energy Commission, Buenos Aires
Sponsoring Organization:
USDOE
NSA Number:
NSA-16-005279
OSTI ID:
4814445
Journal Information:
Analytical Chemistry, Journal Name: Analytical Chemistry Journal Issue: 1 Vol. 34; ISSN 0003-2700
Publisher:
American Chemical Society (ACS)
Country of Publication:
Country unknown/Code not available
Language:
English

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