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Treatment of PAHs in waters using the GAC-FBR process

Conference ·
OSTI ID:479339
 [1]; ; ; ;  [2];  [3];  [4]
  1. EFX Systems, Inc., Lansing, MI (United States)
  2. Michigan Biotechnology Inst., Lansing, MI (United States)
  3. Remediation Technologies, Inc., Concord, MA (United States)
  4. Gas Research Inst., Chicago, IL (United States)

Pilot studies were conducted to determine the utility of the granular activated carbon fluidized-bed reactor (GAC-FBR) process to treat groundwater from manufactured gas plant (MGP) sites containing polycyclic aromatic hydrocarbons (PAHs) and a process effluent water from a deep subsurface dense, nonaqueous-phase liquid (DNAPL) removal process at an MGP site. Removal of naphthalene exceeded 99.9%, and overall PAH removals of 99+% were observed at organic loading rates (OLRs) exceeding 4-kg chemical oxygen demand (COD)/m{sup 3}-d and a hydraulic retention time (HRT) of about 6 min. Analysis of PAHs accumulated on GAC and oxygen consumption clearly demonstrated that removal of 2- to 4-ring PAHs was due primarily to biological oxidation and not to adsorption. Analysis of influent and effluent samples using Microtox{reg_sign} indicated removal of toxicity. Full-scale application of the GAC-FBR process has begun at a Superfund site in Pennsylvania. The GAC-FBR is being used to treat a 15-gal per min (gpm) process effluent flow from a subsurface DNAPL removal process. Initial results confirm the ability of the process to treat PAHs at high OLRs and short HRTs.

OSTI ID:
479339
Report Number(s):
CONF-950483--; ISBN 1-57477-010-1
Country of Publication:
United States
Language:
English

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