Photodissociation and photoinduced electron detachment in dinuclear metal carbonyl anions
- Univ. of Arizona, Tucson, AZ (United States)
The results of visible and near-infrared photochemistry studies of M{sub 2}(CO){sub n}{sup {minus}} compounds (M = Cr, Mn, Fe, Co, 4 {le} n {le} 9) are presented. The authors show that {open_quotes}neutral metal atom loss{close_quotes} from representative anions in this class occurs by electron detachment followed by loss of a neutral metal carbonyl. It is further shown that the electron detachment process can be vibrationally driven.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 476866
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 21 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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