Polarized optical spectra, transition line strengths, and the electronic energy-level structure of Eu(dpa){sub 3}{sup 3-} complexes in single crystals of hexagonal Na{sub 3}[Yb{sub 0.95}Eu{sub 0.05}(dpa){sub 3}]{center_dot}NaClO{sub 4}{center_dot}10H{sub 2}O
- Univ. of Virginia, Charlottesville, VA (United States)
Polarized emission and absorption spectroscopy of 4f{sup 6} Eu{sup 3+} in Na{sub 3}[Yb{sub 0.95}Eu{sub 0.05}(dpa){sub 3}]{center_dot}NaClO{sub 4}{center_dot}10H{sub 2}O (dpa = dipicolinate) is reported with the objective of characterizing the crystal-field energy levels. Empirical and theoretical studies were compared by fitting a parameterized Hamiltonian to the data.
- OSTI ID:
- 476858
- Journal Information:
- Inorganic Chemistry, Vol. 35, Issue 18; Other Information: PBD: 28 Aug 1996
- Country of Publication:
- United States
- Language:
- English
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