Electron Spin Resonance in an Irradiated Single Crystal of Tetramethyl Ammonium Chloride
Journal Article
·
· Journal of Chemical Physics
An-analysis of the electron spin resonance spectrum of gamma - irradiated crystals of N(CH₃)₃Cl shows that the paramagnetic species stable at room temperature is (CH₃)₃N⁺. The isotropic coupling constants are found to be 18.0 G for the nitrogen and 26.7 G for the methyl protons. All methyl protons are found to be equivalent. The radical is probably planar and is found to execute restricted rotation at room tempe rnture. (auth)
- Research Organization:
- Brookhaven National Lab., Upton, N.Y.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-012340
- OSTI ID:
- 4761007
- Report Number(s):
- BNL-6402; 0021-9606
- Journal Information:
- Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 3 Vol. 38; ISSN JCPSA6; ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
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