DEPOSITION OF VARIOUS RADIOACTIVE ELEMENTS ON THE SURFACE OF THE PLATINUM ANODE
Journal Article
·
· Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron
The anodic deposition of Tl/sup 204/, Ce/sup 144/, Y/sup 90/, Yb/sup 175/ , Pr/sup 143/ Pm /sup 147/, and Ho/sup 166/ was investigated as a function of time, with special consideration of Tl/sup 204/ and Ce/sup 144/. These studies show that when these atoms are anodically deposited, a plot of the equilibrium distribution coefficient as a function of the applied voltage passes through a maximum. The number of active centers on the surface of the platinum anode was determined for the anodic deposition of Tl/sup 204/ and Ce/sup 144/ by the isotherm method. A plot of the number of active centers as a function of the applied voltage also gave a curve with a maximum. The effect of hydrogen ion concentration was also investigated and a linear relation between the pH and the logarithm of the number of active centers found. rnvestigation of the deposition of Tl/sup 204/ on platinum from a solution containing hydrogen peroxide shows that the chemisorbed oxide layer, which develops on the platinum anode, plays an important role in the anodic deposition. (auth)
- Research Organization:
- Kossuth Univ., Debrecen, Hungary
- NSA Number:
- NSA-17-018204
- OSTI ID:
- 4743039
- Journal Information:
- Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron, Journal Name: Journal of Inorganic and Nuclear Chemistry (England) Merged with Inorg. Nucl. Chem. Lett. to form Polyhedron Vol. Vol: 24; ISSN JINCA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
PREPARATION OF CARRIER-FREE RADIOACTIVE ATOMIC PRODUCTS BY ELECTROCHROMATOGRAPHIC METHODS USING AN ANODIC POLARISED PLATINUM POWDER COLUMN
RADIOMETRIC METHOD OF DETERMINING ISOTOPIC CONTENT OF Ce SEPARATED FROM HEAVY NUCLEUS FISSION PRODUCTS
HIGH ALTITUDE BALLOON SAMPLING PROGRAM. Quarterly Report No. 2
Journal Article
·
Sun Dec 31 23:00:00 EST 1961
· Magy. Kem. Folyoirat
·
OSTI ID:4654942
RADIOMETRIC METHOD OF DETERMINING ISOTOPIC CONTENT OF Ce SEPARATED FROM HEAVY NUCLEUS FISSION PRODUCTS
Journal Article
·
Sun Dec 31 23:00:00 EST 1961
· Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.)
·
OSTI ID:4762787
HIGH ALTITUDE BALLOON SAMPLING PROGRAM. Quarterly Report No. 2
Technical Report
·
Sun Mar 31 23:00:00 EST 1963
·
OSTI ID:4733323