KINETIC TRACER INVESTIGATIONS ON COMPETING REACTIONS INVOLVING CERTAIN RADICALS
Journal Article
·
· Intern. J. Appl. Radiation Isotopes
Certain competing reactions involving CH/sub 3/CO, CH/sub 3/, CH/sub 3/ OO. and H radicals were studied using the kinetic tracer method. It was shown that for the reaction CH/sub 3/CO + O/sub 2/ the activation energy is 8 kcal/mole and the preexponential factor is 10/sup -10/ cm/sup 3/ sec/sup -1/. The methyl radicalls in a mixture of C/sub 3/H/sub 6/ and O/sub 2/ at 315 deg C yield mainly oxygencontaining products and only small amounts of methane. The CH/sub 3/OO. radicals in the same mixture yieid formaldehyde and methanol at an approximately equal probability. Rite constants for reactions H + C/sub 2/H/sub 4/ yields C/ sub 2/H/sub 5/ and H + C/sub 3/H/sub 6/ yields C/sub 3/H/sub 7/ at 554 deg C are approximately the same. (au th)
- Research Organization:
- Inst. of Chemical Physics, Moscow
- NSA Number:
- NSA-17-006071
- OSTI ID:
- 4737537
- Journal Information:
- Intern. J. Appl. Radiation Isotopes, Journal Name: Intern. J. Appl. Radiation Isotopes Vol. Vol: 13
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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