ISOTOPE EFFECTS ON INTERMOLECULAR INTERACTIONS AND ISOTOPIC VAPOR PRESSURE DIFFERENCES
Technical Report
·
OSTI ID:4735648
The isotope effect on the van der Waals interaction resulting from vibrational excitation terms is discussed to show that it is a zero-point energy effect. Interaction between rotationai, transiational, and vibrational motion in the condensed phase is also discussed in terms of a simple model. By the use of approximation methods, the order of magnitude of these effects is demonstrated and it is shown that consideration of them is of importance in connection with vapor pressure isotope effects. Some other origins of vapor pressure isotope effects are cursorily discussed. (auth)
- Research Organization:
- Brookhaven National Lab., Upton, N.Y.
- DOE Contract Number:
- AT(30-2)-GEN-16
- NSA Number:
- NSA-17-007990
- OSTI ID:
- 4735648
- Report Number(s):
- BNL-6159
- Country of Publication:
- United States
- Language:
- English
Similar Records
ISOTOPE EFFECTS ON INTERMOLECULAR INTERACTIONS AND ISOTOPIC VAPOR PRESSURE DIFFERENCES
Isotope separation by photodissociation of Van der Waal's molecules
Isotope separation by photodissociation of Van der Wall's molecules
Technical Report
·
Tue Oct 30 23:00:00 EST 1962
·
OSTI ID:4816936
Isotope separation by photodissociation of Van der Waal's molecules
Patent
·
Fri Dec 31 23:00:00 EST 1976
·
OSTI ID:862869
Isotope separation by photodissociation of Van der Wall's molecules
Patent
·
Mon Jun 27 20:00:00 EDT 1977
·
OSTI ID:5386023