TRANSFERENCE NUMBERS AND ION ASSOCIATION IN PURE FUSED ALKALINE EARTH CHLORIDES
The transference number of the chloride ion was determined in pure fused MgCl/sub 2/, CaCl/sub 2/, SrCl/sub 2/, and BaCl/sub 2/ utili zing radioactive chloride ions in a porous quartz membrane cell. On the basis of a two-step dissociation for these salts, MCl/sub 2/ in equilibrium MCl/sup +/ + Cl/sup -/ in equilibrium Ml/sup +/ + 2Cl/sup -/, the ext ent of the second dissociation was qualitatively predicted from a consideration of the relative mobilities of the ions. (auth)
- Research Organization:
- Ames Lab., Ames, Iowa
- DOE Contract Number:
- W-7405-ENG-82
- NSA Number:
- NSA-17-007994
- OSTI ID:
- 4735616
- Report Number(s):
- IS-443
- Country of Publication:
- United States
- Language:
- English
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