THE ANION EXCHANGE OF METAL COMPLEXES. XI. APPLICATION OF THE CONSTANT IONIC MEDIUM METHOD TO THE MERCURY HALIDE SYSTEM
The possibilities of the application of the constant ionic medium method to investigations of metal complex formation by anion exchange were studied. In the case of the mercury-- halide systems, it was necessary to use constants determined by another method, in order to determine stability constants for the resin phase, and using these, the constants for severai ionic strengths. In principle, however, knowing the selectivity of the resin with respect to ligand and medium anions, the equations derived should allow the constants to be calculated independently. For this calculation it is necessary to know the variation of the distribution coefficients of tracer metal with ligand concentration under conditions of constant ionic strength of the ouside solution and limited substitution of medium anions by ligand anions. (auth)
- Research Organization:
- Israel. Atomic Energy Commission, Rehovoth
- NSA Number:
- NSA-17-014207
- OSTI ID:
- 4734500
- Report Number(s):
- IA-782
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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