Oxidation-Reduction Reactions of Complex Ammines of Ruthenium(II)-(III)
Journal Article
·
· Journal of the American Chemical Society
The reductions of STARu(NH/sub 3/)/sub 6/!/sup 3+/, STARu(NH/sub 3/)/sub 5/Cl!/sup 2 +/, and o have 1: 1 stoichiometry, and the specific rates of the reductions were measured. By reoxidation of the Ru/sup 2+/ species, it was found thnt the Ru/sup 2+/-NH/sub 3/ bonds remain intact in acid solution for nt least 1 hr, and the oxidation rate with ClO/sub 4/ was measured. The reaction (Ru(NH/sub 3/)/sub 5/H/sub 2/O!/sup 3+/ + Cl/sup -/ yields (Ru(NH/sub 3/)/sub 5/Cl!/sup 2+/ + H/sub 2/O is catalyzed by STARu(NH/sub 3/)/sub 5/!/sup 2+/, and the equilibrium constant was found to be 43 plus or minus 3 at 25 deg C and mu =0.1. (D.L.C.)
- Research Organization:
- Stanford Univ., Calif.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-012243
- OSTI ID:
- 4708468
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 24 Vol. 84; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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