RUTHENIUM RED
Journal Article
·
· Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.
Experiments show that the ruthenium red cation is STARu/sub 3/O/sub 2/ (NH/sub 3/)/sub 1//sub 4/!/sup 6//sup +/ in which there are two oxo-bridges and the average oxidation number of ruthenium is +10/3. The cation is oxidized reversioly by a one-electron to the more paramagnetic brown cation STARu/sub 3/O/ sub 2/(NH)/sub 3//sub 1//sub 4/!/sup 7//sup +/. The relation to other polynuclear complexes is discussed. (auth)
- Research Organization:
- Atomic Energy Research Establishment, Harwell, Berks, Eng.
- NSA Number:
- NSA-15-022296
- OSTI ID:
- 4041774
- Journal Information:
- Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc., Journal Name: Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc.; ISSN JCSOA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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