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Effect of powder characteristics on the {alpha}-TO-{beta} Si{sub 3}N{sub 4} transformation kinetics

Technical Report ·
DOI:https://doi.org/10.2172/463657· OSTI ID:463657
{beta}-phase nucleation and growth is an important step in the microstructure development of Si{sub 3}N{sub 4} ceramics. Samples containing different powder types, sintering additives and {alpha}/{beta} ratios were heated at intermediate temperatures and times to monitor the phase changes taking place. The rate of transformation was mainly dependent on the powder surface area and starting {beta}-content. It was observed that additions of {beta}-Si{sub 3}N{sub 4} increased the rate of transformation.
Research Organization:
Oak Ridge National Lab., TN (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States)
DOE Contract Number:
AC05-96OR22464
OSTI ID:
463657
Report Number(s):
CONF-970111--11; ON: DE97004728
Country of Publication:
United States
Language:
English

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