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Radiolysis of the Iron Pentacarbonyl and Nickel Tetracarbonyl. I. Communication on Radiochemical Investigations of Metal Carbonyls (in German)

Journal Article · · Zeitschrift fuer Physikalische Chemie
The effects of Co/sup 60/ gamma radiation on iron pentacarbonyl and nickel tetracarbonyl were investigated. Iron pentacarbonyl decomposed into CO, Fe/sub 2/(CO)/sub 9/, and Fe/sub 3/(CO)/sub 12 In contrast nickel tetracarbonyl was not appreciably changed by ionizing radiation. The reactor mechanisms deduced from the experimental results are discussed.
Research Organization:
Universitat, Cologne (Germany)
NSA Number:
NSA-17-039145
OSTI ID:
4628281
Journal Information:
Zeitschrift fuer Physikalische Chemie, Journal Name: Zeitschrift fuer Physikalische Chemie Journal Issue: 1-2 Vol. 38; ISSN 0942-9352
Country of Publication:
Germany
Language:
German