Energy Transfer Between Hydrocarbons and Metal Carbonyls. II. Report on Radiochemical Investigation of Metal Carbonyls

Journal Article · Fri Nov 01 04:00:00 EST 1963 · Zeitschrift fuer Physikalische Chemie

DOI:https://doi.org/10.1524/zpch.1963.39.3_4.148· OSTI ID:4084973

Barzynski, H; Hummel, D

The effects of Co⁶⁰ gamma radiation on mixtures of cyclohexahe with iron pentacarbonyl or nickel tetracarbonyl were investigated. The G values of the most impontant reaction products, cyclohexene, dicyclohexyl, carbon monoxide, iron monocarbonyl, iron dodecacarbonyl, and elementary nickel, were determined in relation to their dependence on mixture content and the absorbed radiation energy. The results obtained showed that the energy primarily absorbed by the cyclohexane is in pant transferred from the metal carbonyl. A kinetic consideration yielded insight into the mechanism of the reaction.

• Research Organization: Universitat, Cologne
• NSA Number: NSA-18-013893
• OSTI ID: 4084973
• Journal Information: Zeitschrift fuer Physikalische Chemie, Journal Name: Zeitschrift fuer Physikalische Chemie Journal Issue: 3_4 Vol. Vol: 39; ISSN 0942-9352
• Country of Publication: Country unknown/Code not available
• Language: German

Related Subjects

ABSORPTION
CARBON MONOXIDE
CARBONYLS
CHEMISTRY
COBALT 60
COMPOUNDS
CYCLOALKANES
CYCLOALKENES
DECOMPOSITION
DIAGRAMS
EFFICIENCY
ENERGY
GAMMA RADIATION
GAMMA SOURCES
HEXANE
HYDROCARBONS
IRON COMPOUNDS
IRRADIATION
MEASURED VALUES
METALS
MIXING
NICKEL
NICKEL COMPOUNDS
RADIATION CHEMISTRY
RADIOLYSIS
REACTION KINETICS
SOLVENTS
TRANSPORT THEORY